cyclopenta-1,3-diene,ditert-butyl-[5-[(1S)-1-diphenylphosphanylethyl]cyclopenta-1,3-dien-1-yl]phosphane,iron(2+) - Names and Identifiers
cyclopenta-1,3-diene,ditert-butyl-[5-[(1S)-1-diphenylphosphanylethyl]cyclopenta-1,3-dien-1-yl]phosphane,iron(2+) - Physico-chemical Properties
Molecular Formula | C32H34FeP2
|
Molar Mass | 536.42 |
Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
cyclopenta-1,3-diene,ditert-butyl-[5-[(1S)-1-diphenylphosphanylethyl]cyclopenta-1,3-dien-1-yl]phosphane,iron(2+) - Risk and Safety
WGK Germany | 3 |
HS Code | 29319090 |
cyclopenta-1,3-diene,ditert-butyl-[5-[(1S)-1-diphenylphosphanylethyl]cyclopenta-1,3-dien-1-yl]phosphane,iron(2+) - Introduction
(1S)-1-[BIS(1,1-DIMETHYLETHYL)PHOSPHINO]-2-[(1S)-1-(DIPHENYLPHOSPHINO)ETHYL]FERROCENE is a chiral organic compound named after the chemical formula [(S)-P]-[(R)-Cp]-[(PPH₂)-Et]. It has the following properties and applications:
Nature:
-Appearance: usually solid, orange or red in color.
-Melting point: about 130-135°C.
-Solubility: Soluble in non-polar organic solvents, such as ether and dichloromethane.
-Stable for air and moisture.
Use:
-Chiral ligand: It can be used as a chiral ligand in metal organic catalytic reactions, such as asymmetric hydrogenation, asymmetric catalytic reduction, etc.
-Catalyst: used to catalyze the coupling reaction of halogenated hydrocarbons, asymmetric catalytic carbonylation reaction, hydrogenation reaction, etc.
-Synthesis of heterocyclic compounds: It can be used to synthesize chiral heterocyclic compounds containing metallocene groups and organic phosphorus groups.
Preparation Method:
the preparation method of (1S)-1-[BIS(1,1-DIMETHYLETHYL)PHOSPHINO]-2-[(1S)-1-(DIPHENYLPHOSPHINO)ETHYL]FERROCENE is relatively complicated. the common synthesis routes include the reaction of metallocyllithium with bromobenzene, the reaction of ferrocene with acetylene, the reaction of 1,1-di-tert-butylphosphine compound with haloalkane, etc. The specific preparation method requires in-depth research and experiments.
Safety Information:
The safety of the- (1S)-1-[BIS(1,1-DIMETHYLETHYL)PHOSPHINO]-2-[(1S)-1-(DIPHENYLPHOSPHINO)ETHYL]FERROCENE was good.
-Take necessary safety precautions during operation, such as wearing appropriate protective glasses and gloves.
-Avoid prolonged contact with skin and inhalation of dust, and wash thoroughly after use.
-During storage, avoid contact with fire sources, oxidants and other substances, and keep the container sealed.
Please note that because the preparation method of this compound is more complicated and involves professional knowledge and experimental techniques in the field of organic synthesis, it is not recommended for non-professionals to prepare or use this compound.
Last Update:2024-04-10 22:29:15